Publications
2024
648. "[Cu(NHC)(OR)] (R = C(CF3)3) complexes for N–H and S–H bond activation and as pre-catalysts in the Chan–Evans–Lam reaction." Ruggiero, T.; Van Hecke, K.; Cazin, C. S. J.; Nolan, S. P. Dalton Trans., 2024, Advance Article.
647. "Machine learning directed discovery and optimisation of a platinum-catalysed amide reduction." Casillo, E.; Maliszewski, B. P.; Urbina-Blanco, C. A.; Scattolin, T.; Cazin, C. S. J.; Nolan, S. P. ChemComm., 2024, Advance Article.
646. "The role of the stabilizing/leaving group in palladium catalysed cross-coupling reactions." Palio, L.; Bru, F.; Ruggiero, T.; Bourda, L.; Van Hecke, K.; Cazin, C.; Nolan, S. P. Dalton Trans., 2024, 53, 18013–18020.
645. "Modular Synthesis of Azines Bearing a Guanidine Core from N-Heterocyclic Carbene (NHC)-Derived Selenoureas and Diazo Reagents." Tonis, E.; Tzouras, N. V.; Bracho Pozsoni, N.; Saab, M.; Bhandary, S.; Van Hecke, K.; Nelson, D. J.; Nahra, F.; Nolan, S. P.; Vougioukalakis, G. C. Chem. Eur. J., 2024, 30, e202401816.
644. "Synthesis and reactivity of N-heterocyclic carbene (NHC) gold-fluoroalkoxide complexes." Arnaut, P.; Bracho Pozsoni, N.; Nahra, F.; Tzouras, N. V.; Nolan, S. P. Dalton Trans., 2024, 53, 11952–11958.
643. "Synthesis of N-heterocyclic carbene (NHC)-Au/Ag/Cu benzotriazolyl complexes and their catalytic activity in propargylamide cycloisomerization and carbonyl hydrosilylation reactions." Kaplanai, E.; Tzouras, N. V.; Tsoureas, N.; Bracho Pozsoni, N.; Bhandary, S.; Van Hecke, K.; Nolan, S. P.; Vougioukalakis, G. C. Dalton Trans., 2024, 53, 11001–11008.
642. "Dinuclear NHC-gold(I)-thiolato and -alkynyl complexes: synthesis, anticancer activity, and catalytic activity in lactonization reactions." Ma, X.; Zhao, Y.; Caligiuri, I.; Rizzolio, F.; Bracho Pozsoni, N.; Van Hecke, K.; Scattolin, T.; Nolan, S. P. Dalton Trans., 2024, 53, 7939–7945.
641. "Synthesis of cyclobutane-fused chromanones via gold-mediated photocatalysis." Voloshkin, V. A.; Villa, M.; Martynova, E. A.; Beliš, M.; Van Hecke, K.; Ceroni, P.; Nolan, S. P. Chem. Sci., 2024, 15, 4571–4580.
640. "Synthesis of cyclohepta[b]indoles via gold mediated energy transfer photocatalysis." Zhao, Y.; Voloshkin, V. A.; Martynova, E. A.; Maity, B.; Cavallo, L.; Nolan, S. P. Chem. Commun., 2024, 60, 3174–3177.
639. "Telomerization of butadiene with ethanol mediated by palladium N-heterocyclic carbene catalysts." Palio, L.; Dumont, C.; Suisse, I.; Sauthier, M.; Nolan, S. P. J. Catal., 2024, 429, 115216.
638. "Continuous Flow Synthesis of Group 11 Metal-NHC Complexes [M(IPr)(OC(H)(CF3)2)] (with M=Cu, Ag and Au)." Simoens, A.; Carì, G.; Ostrowska, S.; Cazin, C. S. J.; Stevens, C. V.; Nolan, S. P. Asian J. Org. Chem., 2024, 13, e202400013.
2023
637. "Simply accessible platinum(ii) complexes enabling alkene hydrosilylation at ppm catalyst loadings." Maliszewski, B. P.; Casillo, E.; Lambert, P.; Nahra, F.; Cazin, C. S. J.; Nolan, S. P. Chem. Commun., 2023, 59, 14017–14020.
636. "Palladates of the [NHC⋅H][Pd(NH2)(CC)Cl2] Type as Effective Pre-catalysts for the Formation of C−C and C−N Bonds." Ostrowska, S.; Czapik, A.; Kwit, M.; Nolan, S. P. ChemCatChem, 2023, 15, e202301124.
635. "Gold(I)-N-Heterocyclic Carbene Synthons in Organometallic Synthesis." Scattolin, T.; Tonon, G.; Botter, E.; Guillet, S. G.; Tzouras, N. V.; Nolan, S. P. Chem. Eur J., 2023, 29, e202301961.
634. "Advances in the Synthesis and Applications of N-Heterocyclic Carbene Metal Complexes with a Focus on the Weak Base Route." Scattolin, T.; Logvinov, A. A.; Tzouras, N. V.; Cazin, C. S. J.; Nolan, S. P. Organometallics, 2023, 42, 2692–2730.
633. "PtII−N‐Heterocyclic Carbene Complexes in Solvent‐Free Alkene Hydrosilylation." Maliszewski, B. P.; Bayrakdar, T. A. C. A.; Lambert, P.; Hamdouna, L.; Trivelli, X.; Cavallo, L.; Poater, A.; Beliš, M.; Lafon, O.; Van Hecke, K.; Ormerod, D.; Cazin, C. S. J.; Nahra, F.; Nolan, S. P. Chem. Eur J., 2023, 29, e202301259.
632. "An Air-Stable [Cu(NHC)(OR)] (R = C(H)(CF3)2) Complex for C–H, N–H and S–H Bond Activation." Ostrowska, S.; Arnaut, P.; Liptrot, D. J.; Cazin, C. S. J.; Nolan, S. P. Chem. Commun., 2023, 59, 9126–9129.
631. "Exploiting the Inductive Effect of the Trifluoromethyl Group: Regioselective Gold-Catalyzed Hydration of 2,2,2-Trifluoroethyl-Substituted Alkynes." Gauthier, R.; Tzouras, N. V.; Nolan, S. P.; Paquin, J.-F. Chem. Commun., 2023, 59, 9138–9141.
630. "Gold Complexes with Remote-Substituted Amino N-Heterocyclic Carbenes." Vanden Broeck, S. M. P.; Tzouras, N. V.; Saab, M.; Van Hecke, K.; Dereli, B.; Ritacco, I.; Cavallo, L.; Vougioukalakis, G. C.; Braunstein, P.; Nolan, S. P.; Danopoulos, A. A.; Cazin, C. S. J. Dalton Trans., 2023, 52, 9908–9912.
629. "Site selective gold(I)-catalysed benzylic C–H amination via an intermolecular hydride transfer to triazolinediones." Bevernaege, K.; Tzouras, N. V.; Poater, A.; Cavallo, L.; Nolan, S. P.; Nahra, F.; Winne, J. M. Chem. Sci., 2023, 14, 9787–9794.
628. "Synthesis, Characterization, and Reactivity of [Pd(Phosphine)(Py)Cl2] (PEPPSI) and [Pd(Phosphine)Cl2]2 Complexes." Voloshkin, V. A.; Liu, Y.; Beliš, M.; Peng, M.; Van Hecke, K.; Cazin, C. S. J.; Nolan, S. P. Dalton Trans., 2023, 52, 3690–3698.
627. "Mechanistic Insights into the Synthesis of [Rh(Acac)(CO)(NHC)] (NHC=N‐heterocyclic Carbene) Complexes Using a Weak Base." Guillet, S. G.; Ibni Hashim, I.; Beliš, M.; Van Hecke, K.; Cazin, C. S. J.; Nolan, Steven. P. Eur. J. Inorg. Chem., 2023, 26, e202300327.
626. "Regioselective 1,2-Hydrosilylation of N-Heterocycles Catalyzed by a Ruthenium Olefin Metathesis Catalyst." Ma, X.; Nolan, S. P. Organometallics, 2023, 42, 1978–1984.
625. "Suzuki–Miyaura Cross-Coupling of Amides by N–C Cleavage Mediated by Air-Stable, Well-Defined [Pd(NHC)(Sulfide)Cl2] Catalysts: Reaction Development, Scope, and Mechanism." Yang, S.; Yu, X.; Liu, Y.; Tomasini, M.; Caporaso, L.; Poater, A.; Cavallo, L.; Cazin, C. S. J.; Nolan, S. P.; Szostak, M. J. Org. Chem., 2023, 88, 10858–10868.
624. "Hexafluoroisopropanol (HFIP) as a Multifunctional Agent in Gold-Catalyzed Cycloisomerizations and Sequential Transformations." Tzouras, N. V.; Zorba, L. P.; Kaplanai, E.; Tsoureas, N.; Nelson, D. J.; Nolan, S. P.; Vougioukalakis, G. C. ACS Catal., 2023, 13, 8845–8860.
623. "Controlled Cluster Compositions." Nolan, S. P. Nat. Synth, 2023, 2, 701–702.
622. "Deep Red to Near-Infrared Light-Controlled Ruthenium-Catalyzed Olefin Metathesis." Cabanero, D. C.; Nguyen, J. A.; Cazin, C. S. J.; Nolan, S. P.; Rovis, T. ACS Catal., 2023, 13, 4384–4390.
621. "Access to Azetidines via Gold Mediated Energy Transfer Photocatalysis." Guillet, S. G.; Logvinov, A. A.; Voloshkin, V. A.; Martynova, E. A.; Nolan, S. P. Org. Lett., 2023, 25, 1403–1408.
620. “A second-generation palladacycle architecture bearing a N-heterocyclic carbene and its catalytic behavior in Buchwald-Hartwig amination catalysis.” Ostrowska, S.; Palio, L.; Czapik, A.; Bhandary, S.; Kwit, M.; Van Hecke, K.; Nolan, S. P. Catalysts, 2023, 13, 559.
619. “Ruthenium-Catalyzed Regioselective 1, 2-Hydrosilylation of N-Heteroarenes.” Ma, X.; Mane, M. V.; Cavallo, L. C.; Nolan, S. P. Eur. J. Org. Chem., 2023, e202201466.
618. “Liquid Dynamics Determine Transition Metal-N-Heterocyclic Carbene Complex Formation.” Zaby, P.; Müller, A.; Blasius, J.; Nolan, S. P.; Hollóczki, O. Chem. Eur. J., 2023, e202203636.
2022
617. “One-Pot Multicomponent Synthesis of Allyl and Alkylamines Using a Catalytic System Composed of Ruthenium Nanoparticles on Copper N-Heterocyclic Carbene-Modified Silica.” Kalsi, D.; Weidenthaler, C.; Emondts, M.; Nolan, S. P.; Bordet, A.; Leitner, W. ACS Catal., 2022, 12, 14902–14910.
616. “N-Heterocyclic Carbene Gold Complexes in a Photocatalytic CO2 Reduction Reaction.” Nugego.da, D.; Tzouras, N. V.; Nolan, S. P.; Delcamp, J. H. Inorg. Chem., 2022, 61, 18802–18809.
615. “Unveiling the potential of gold(I) and silver(I) selenourea complexes as anticancer agents targeting TrxR and cellular redox homeostasis.” Saab, M.; De Franco, M.; Grana, S.; Porchia, M.; Van Hecke, K.; Nolan, S. P.; Gandin, V.; Nahra, F. Chem. Eur. J., 2022, e202201898.
614. “Merging gold(I) catalysis with amine transaminases in cascade catalysis: Chemoenzymatic transformation of propargylic alcohols into enantioenriched allylic amines.” González-Granda; S.; Tzouras, N. V.; Nolan, S. P.; Lavander, I.; Gotor-Fernández, V. Adv. Synth. Catal., 2022, 364, 3856–3866 (e202200777).
613. “Silver-catalyzed site-selective C(sp3)−H benzylation of ethers with N-triftosylhydrazones.” Liu, Z.; Wang, H.; Sivaguru, P.; Nolan, S. P.; Song, Q.; Yu, W.; Jiang, X.; Anderson, E. A.; Bi, X. Nature Comm., 2022, 13, 1674.
612. “Indenyl and allyl palladate complexes bearing N-heterocyclic carbene ligands: an easily accessible class of new anticancer drug candidates.” Scattolin, T.; Pessotto, I.; Cavarzerani, E.; Canzonieri, V.; Orian, L.; Demitri, N.; Cazini, A.; Rizzolio, F.; Nolan, S. P.; Visentin, F. Eur. J. Inorg. Chem., 2022, 28, e202100840.
611. "Energy Transfer (EnT) Photocatalysis Enabled by Gold-N-Heterocyclic Carbene (NHC) Complexes." Martynova, E. A.; Voloshkin, V. A.; Guillet, S. G.; Bru, F.; Beliš, M.; Van Hecke, K.; Cazin, C. S. J.; Nolan, S. P. Chem. Sci., 2022, 13, 6852–6857.
610. "Hydrogen Bonding-Enabled Gold Catalysis: Ligand Effects in Gold-Catalyzed Cycloisomerizations in Hexafluoroisopropanol (HFIP)." Tzouras, N. V.; Gobbo, A.; Pozsoni, N. B.; Chalkidis, S. G.; Bhandary, S.; Van Hecke, K.; Vougioukalakis, G. C.; Nolan, S. P. Chem. Commun., 2022, 58, 8516-8519.
609. "Improved Synthetic Routes to N-Heterocyclic Carbene-Metal-Diketonato Complexes of Gold and Copper." Ibni Hashim, I.; Tzouras, N. V.; Ma, X.; Bourda, L.; Van Hecke, K.; Nolan, S. P.; Cazin, C. S. J. Dalton Trans., 2022, 51, 13246–13254.
608. "Theoretical Study on the Mechanism, Chemo- and Enantioselectivity of the Ag- vs. Rh-Catalyzed Intramolecular Carbene Transfer Reaction of Diazoacetamides." Song, Q.; Wu, J.; Tzouras, N. V.; Wu, Y.; Nolan, S. P. RSC Adv., 2022, 12, 18197–18208.
607. "Synthesis of Carbene‐Metal‐Amido (CMA) Complexes and Their Use as Precatalysts for the Activator‐Free, Gold‐Catalyzed Addition of Carboxylic Acids to Alkynes." Ibni Hashim, I.; Tzouras, N. V.; Janssens, W.; Scattolin, T.; Bourda, L.; Bhandary, S.; Van Hecke, K.; Nolan, S. P.; Cazin, C. S. J. Chem. Eur. J., 2022, 28, e202201224.
606. "Flow Chemistry of Main Group and Transition Metal Complexes." Scattolin, T.; Simoens, A.; Stevens, C. V.; Nolan, S. P. Trends Chem., 2022, 4, 584–607.
605. "Versatile and Highly Efficient Trans ‐[Pd(NHC)Cl 2 (DMS/THT)] Precatalysts for C−N and C−C Coupling Reactions in Green Solvents." Liu, Y.; Voloshkin, V. A.; Scattolin, T.; Peng, M.; Van Hecke, K.; Nolan, S. P.; Cazin, C. S. J. Eur. J. Org. Chem., 2022, e202200309.
604. "A green route to platinum N-heterocyclic carbene complexes: mechanism and expanded scope." Maliszewski, B. P.; Ritacco, I.; Beliš, M.; Hashim, I. I.; Tzouras, N. V.; Caporaso, L.; Cavallo, L.; Van Hecke, K.; Nahra, F.; Cazin, C. S. J.; Nolan, S. P. Dalton Trans., 2022, 51, 6204–6211.
603. "Azolium Aurates as Pre-Catalysts for the Oxidative Coupling of Terminal Alkynes under Mild Conditions." Ma, X.; Tzouras, N. V.; Peng, M.; Van Hecke, K.; Nolan, S. P. J. Org. Chem., 2022, 87, 4883–4893.
602. "A simple synthetic entryway into (N-heterocyclic carbene)gold-steroidyl complexes and their anticancer activity." Scattolin, T.; Lippmann, P.; Beliš, M.; van Hecke, K.; Ott, I.; Nolan, S. P. Appl Organomet Chem., 2022, e6624.
601. "Continuous Flow Synthesis of Sulfur- and Selenium−NHC Compounds (NHC=N-Heterocyclic Carbene)." Cauwenbergh, T.; Scattolin, T.; Simoens, A.; Tzouras, N. V.; Stevens, C. V.; Nolan, S. P. Eur. J. Org. Chem., 2022, 2022, 15–20.
600. "Continuous Flow Synthesis of NHC-Coinage Metal Amido and Thiolato Complexes: A Mechanism-based Process Development." Cauwenbergh, T.; Tzouras, N. V.; Scattolin, T.; Simoens, A.; Stevens, C. V.; Cazin, C. S. J.; Nolan, S. P. Chemistry—Methods, 2022, 2, e202100098.
599. "Gold N-Heterocyclic Carbene Catalysts for the Hydrofluorination of Alkynes Using Hydrofluoric Acid: Reaction Scope, Mechanistic Studies and the Tracking of Elusive Intermediates." Gauthier, R.; Tzouras, N. V.; Zhang, Z.; Bédard, S.; Saab, M.; Falivene, L.; Van Hecke, K.; Cavallo, L.; Nolan, S. P.; Paquin, J. -F. Chem. Eur. J., 2022, 28, e20210388.
598. "A Simple Synthetic Route to Well-Defined [Pd(NHC)Cl(1-tBu-indenyl)] Pre-catalysts for Cross-Coupling Reactions." Liu, Y.; Scattolin, T.; Gobbo, A.; Beliš, M.; Van Hecke, K.; Nolan, S. P.; Cazin, C. S. J. Eur. J. Inorg.Chem., 2022, e202100840.
597. "A simple synthetic entryway into new families of NHC–gold-amido complexes and their in vitro antitumor activity." Martynova, E. A; Scattolin, T.; Cavarzerani, E.; Peng, M.; Van Hecke, K.; Rizzolio, F.; Nolan, S. P. Dalton Trans., 2022, 51, 3462–3471.
596. "Reactions of N-heterocyclic carbene-based chalcogenoureas with halogens: a diverse range of outcomes." Saab, M.; Nelson, D. J.; Leech, M. C.; Lam, K.; Nolan, S. P.; Nahra, F.; Van Hecke, K. Dalton Trans., 2022, 51, 3721–3733.
595. "Straightforward synthesis of [Cu(NHC)(alkynyl)] and [Cu(NHC)(thiolato)] complexes (NHC = N-heterocyclic carbene)." Hashim, I. I.; Scattolin, T.; Tzouras, N. V.; Bourda, L.; Van Hecke, K.; Ritacco, I.; Caporaso, L.; Cavallo, L.; Nolan, S. P.; Cazin, C. S. J. Dalton Trans., 2022, 51, 231–240.
2021
594. "Integrating membrane separation with gold-catalyzed carboxylative cyclization of propargylamine and catalyst recovery via organic solvent nanofiltration." Bayrakdar, T. A. C. A.; Nahra, F.; Ormerod, D.; Nolan, S. P. J Chem Technol Biotechnol, 2021, 96, 3371–3377.
593. "Synthesis of γ, δ-Unsaturated Esters and Amides via Au(I)-Catalyzed Reactions of Aryl Ynol Ethers or Ynamides with Allylic Alcohols." Misawa, S.; Miyairi, A.; Oonishi, Y.; Nolan, S. P.; Sato, Y. Synthesis, 2021, 53, 4644–4653.
592. "Mechanistic Aspects of the Palladium-Catalyzed Suzuki-Miyaura Cross-Coupling Reaction." D'Alterio, M. C.; Casals-Cruañas, È.; Tzouras, N. V.; Talarico, G.; Nolan, S. P.; Poater, A. Chem. Eur. J., 2021, 27, 13481–13493.
591. "A Simple Synthetic Route to [Rh(acac)(CO)(NHC)] Complexes: Ligand Property Diagnostic Tools and Precatalysts." Guillet, S. G.; Pisanò, G.; Chakrabortty, S.; Müller, B. H.; de Vries, J. G.; Kamer, P. C. J.; Cazin, C. S. J.; Nolan, S. P. Eur. J. Inorg. Chem., 2021, 3506–3511.
590. "Continuous Flow Synthesis of [Au(NHC)(Aryl)] (NHC=N-Heterocyclic Carbene) Complexes." Cauwenbergh, T.; Tzouras, N. V.; Scattolin, T.; Bhandary, S.; Simoens, A.; Van Hecke, K.; Stevens, C. V.; Nolan, S. P. Chem. Eur. J., 2021, 27, 13342–13345.
589. "Platinum-Catalyzed Alkene Hydrosilylation: Solvent-Free Process Development from Batch to a Membrane-Integrated Continuous Process." Bayrakdar, T. A. C. A.; Maliszewski, B. P.; Nahra, F.; Ormerod, D.; Nolan, S. P. ChemSusChem, 2021, 14, 3810-3814.
588. "Optimizing Catalyst and Reaction Conditions in Gold(I) Catalysis–Ligand Development." Collado, A.; Nelson, D. J.; Nolan, S. P. Chem. Rev., 2021, 121, 8559–8612.
587. "Fluoroalkyl N-Triftosylhydrazones as Easily Decomposable Diazo Surrogates for Asymmetric [2 + 1] Cycloaddition: Synthesis of Chiral Fluoroalkyl Cyclopropenes and Cyclopropanes." Zhang, X.; Tian, C.; Wang, Z.; Sivaguru, P.; Nolan, S. P.; Bi, X. ACS Catal., 2021, 11, 8527–8537.
586. "Chelation enforcing a dual gold configuration in the catalytic hydroxyphenoxylation of alkynes." Escayola, S.; Poater, J.; Ramos, M.; Luque-Urrutia, J. A.; Duran, J.; Simon, S.; Solà, M.; Cavallo, L.; Nolan, S. P.; Poater, A. Appl Organomet Chem., 2021, 35, e6362.
585. "A critical review of palladium organometallic anticancer agents." Scattolin, T; Voloshkin, V. A.; Visentin, F.; Nolan, S. P. Cell Reports Physical Science, 2021, 2, 100446.
584. "Synthesis of N-heterocyclic carbene gold(I) complexes." Nahra, F.; Tzouras, N. V.; Collado, A.; Nolan, S. P. Nature Protocols, 2021, 16, 1476–1493.
583. "Continuous Flow Synthesis of Metal–NHC Complexes." Simoens, A.; Scattolin, T.; Cauwenbergh, T.; Pisanò, G.; Cazin, C. S. J.; Stevens, C. V.; Nolan, S. P. Chem. Eur. J., 2021, 27, 5653–5657.
Highlighted as “Hot Paper”
582. "A simple synthesis of [RuCl2(NHC)(p-cymene)] complexes and their use in olefin oxidation catalysis." Ma, X.; Guillet, S. G.; Peng, M.; Van Hecke, K.; Nolan, S. P. Dalton Trans., 2021, 50, 3959–3965.
581. "Conversion of Pd(I) off-cycle species into highly efficient cross-coupling catalysts." Liu, Y.; Voloshkin, V. A.; Scattolin, T.; Cavallo, L.; Dereli, B.; Cazin, C. S. J.; Nolan, S. P. Dalton Trans., 2021, 50, 5420–5427.
580. "N-Heterocyclic carbene complexes enabling the α-arylation of carbonyl compounds." Ostrowska, S.; Scattolin, T.; Nolan, S. P. Chem. Commun., 2021, 57, 4354–4375.
579. "Simple Synthesis of [Ru(CO3)(NHC)(p-Cymene)] Complexes and Their Use in Transfer Hydrogenation Catalysis." Ma, X.; Guillet, S. G.; Liu, Y.; Cazin, C. S. J.; Nolan, S. P. Dalton Trans., 2021, 50, 13012–13019.
578. "Recent Advances in the Synthesis and Derivatization of N-Heterocyclic Carbene Metal Complexes." Voloshkin, V. A.; Tzouras, N. V.; Nolan, S. P. Dalton Trans., 2021, 50, 12058–12068.
577. "Suzuki–Miyaura cross-coupling of esters by selective O–C(O) cleavage mediated by air- and moisture-stable [Pd(NHC)(μ-Cl)Cl]2 precatalysts: catalyst evaluation and mechanism." Yang, S.; Zhou, T.; Poater, A.; Cavallo, L.; Nolan, S. P.; Szostak, M. Catal. Sci. Technol., 2021, 11, 3189–3197.
576. "Synthesis and catalytic activity of palladium complexes bearing N-heterocyclic carbenes (NHCs) and 1,4,7-triaza-9-phosphatricyclo[5.3.2.1]tridecane (CAP) ligands." Scattolin, T.; Voloshkin, V. A.; Martynova, E.; Vanden Broeck, S. M. P.; Beliš, M.; Cazin, C. S. J.; Nolan, S. P. Dalton Trans., 2021, 50, 9491–9499.
575. "The “weak base route” leading to transition metal–N-heterocyclic carbene complexes." Martynova, E. A.; Tzouras, N. V.; Pisanò, G.; Cazin, C. S. J.; Nolan, S. P. Chem. Commun., 2021, 57, 3836–3856.
2020
574. "A general protocol for the synthesis of Pt-NHC (NHC = N-heterocyclic carbene) hydrosilylation catalysts." Maliszewski, B. P.; Tzouras, N. V.; Guillet, S. G.; Saab, M.; Beliš, M.; Van Hecke, K.; Nahra, F.; Nolan, S. P. Dalton Trans., 2020, 49, 14673–14679.
573. "Synthesis, reactivity and catalytic activity of Au-PAd3 complexes." Voloshkin, V. A.; Saab, M.; Van Hecke, K.; Lau, S. H.; Carrow, B. P.; Nolan, S. P. Dalton Trans., 2020, 49, 13872–13879.
572. "Dinuclear gold(I) complexes: from bonding to applications." Bayrakdar, T. A. C. A.; Scattolin, T.; Ma, X.; Nolan, S. P. Chem. Soc. Rev., 2020, 49, 7044–7100.
571. "Straightforward access to chalcogenoureas derived from N-heterocyclic carbenes and their coordination chemistry." Saab, M.; Nelson, D. J.; Tzouras, N. V.; Bayrakdar, T. A. C. A.; Nolan, S. P.; Nahra, F.; Van Hecke, K. Dalton Trans., 2020, 49, 12068–12081.
570. "Synthetic Routes to Late Transition Metal–NHC Complexes." Scattolin, T.; Nolan, S. P. Trends Chem., 2020, 2, 721–736.
569. "Using sodium acetate for the synthesis of [Au(NHC)X] complexes." Scattolin, T.; Tzouras, N. V.; Falivene, L.; Cavallo, L.; Nolan, S. P. Dalton Trans., 2020, 49, 9694-9700.
568. “Understanding existing and designing novel synthetic routes to Pd-PEPPSI-NHC and Pd-PEPPSI-PR3 pre-catalysts.” Guillet, S. G.; Voloshkin, V. A.; Saab, M.; Beliš, M.; Van Hecke, K.; Nahra, F.; Nolan, S. P. Chem. Commun., 2020, 56, 5953–5956.
567. “Improving process efficiency of gold-catalyzed hydration of alkynes: merging catalysis with membrane separation.” Bayrakdar, T. A. C. A.; Nahra, F.; Zugazua, O. G.; Eykens, L.; Ormerod, D.; Nolan, S. P., Green Chem., 2020, 22, 2598–2604.
566. “Simple Synthetic Routes to N‐Heterocyclic Carbene Gold(I)–Aryl Complexes: Expanded Scope and Reactivity.” Tzouras, N. V.; Saab, M.; Janssens, W.; Cauwenbergh, T.; Van Hecke, K.; Nahra, F.; Nolan, S. P. Chem. Eur J., 2020, 26, 5541–5551.
Highlighted as “Hot Paper”
Highlighted in Wiley Hot Topic: Gold
565. “A Mechanistically and Operationally Simple Route to Metal–N‐Heterocyclic Carbene (NHC) Complexes.” Tzouras, N. V.; Nahra, F.; Falivene, L.; Cavallo, L.; Saab, M.; Van Hecke, K.; Collado, A.; Collett, C. J.; Smith, A. D.; Cazin, C. S. J.; Nolan, S. P. Chem. Eur J., 2020, 26, 4515–4519.
564. “N-Heterocyclic Carbene (NHC) Complexes in C–H Activation Reactions.” Zhao, Q,; Meng, G.; Nolan, S. P.; Szostak, M. Chem. Rev., 2020, 119, 1981–2048.
563. “Buchwald–Hartwig cross-coupling of amides (transamidation) by selective N–C(O) cleavage mediated by air- and moisture-stable [Pd(NHC)(allyl)Cl] precatalysts: catalyst evaluation and mechanism.” Li, G.; Zhou, T.; Poater, A,; Cavallo, L.; Nolan, S. P.; Szostak, M. Catal. Sci. Technol., 2020, 10, 710–716.
2019
562. “Mizoroki-Heck cross-coupling of acrylate derivatives with aryl halides catalyzed by palladate pre-catalysts.” Islam, M. S.; Nahra, F.; Tzouras, N. V.; Barakat, A.; Cazin, C. S. J.; Nolan, S. P.; Al-Majid, A. M. Eur. J. Inorg. Chem., 2019, 4695–4699.
561. “2-Methyltetrahydrofuran (2-MeTHF): A Green Solvent for Pd–NHC-Catalyzed Amide and Ester Suzuki–Miyaura Cross-Coupling.” Lei, P.; Ling, Y.; An, J.; Nolan, S. P.; Szostak, M. Adv. Synth. Cat., 2019, 361, 5654–5660.
560. “Investigating the Biological Activity of imidazolium aurate salts.” Sioriki, E.; Gaillard, S.; Nahra, F.; Imad, R.; Wajid, S.; Sharif, D.; Fayyad, S.; Arshad, F.; Choudhary, M. I.; Nolan, S. P. Chem. Select, 2019, 4, 11061–11065.
559. “Quantifying electronic similarities between NHC-gold(I) complexes and their isolobal imidazolium precursors.” Azofra, L. M.; Veenboer, R. M. P.; Falivene, L.; Vummaleti, S. V. C.; Poater, A.; Nolan, S. P.; Cavallo. L. Phys. Chem. Chem. Phys. 2019, 21, 15615–15622.
558. “Palladate pre-catalysts for the formation of C-N and C-C bonds.” Zinser, C. M.; Warren, K. G.; Nahra, F.; Al-Majid, A.; Barakat, A.; Islam, M. S.; Nolan, S. P.; Cazin, C. S. Organometallics, 2019, 38, 2812–2817.
557. “Synthesis and Reactivity of [Au(NHC)(Bpin)] Complexes.” Zinser, C. M.; Nahra, F.; Falivene, L.; Brill, M.; Cordes, D. B.; Slawin, A. M. Z.; Cavallo, L.; Cazin, C. S. J.; Nolan, S. P. Chem. Commun., 2019, 55, 6799–6802.
556. “Regression Analysis of Properties of [Au(IPr)(CHR2)] Complexes.” Veenboer, R. M. P.; Azofra, L. M.; Gasperini, D.; Collado, A.; Cordes, D. B.; Slawin, A. M. Z.; Cavallo, L.; Nolan, S. P. Dalton Trans., 2019, 48, 7693–7703.
555. “[Pd(NHC)(acac)Cl]: Well-Defined, Air-Stable and Readily Available Precatalysts for Suzuki and Buchwald-Hartwig Cross-Coupling (Transamidation) of Amides and Esters by N–C/O–C Activation” Zhou, T.; Li, G.; Nolan, S. P.; Szostak, M. Org. Let., 2019, 21, 3304–3309.
554. “Gold(I) catalysed regio- and stereoselective intermolecular hydroamination of internal alkynes: towards functionalised azoles.” Michon, C.; Gilbert, J.; Trivelli, X.; Nahra, F.; Cazin, C. S. J.; Agbossou-Niedercorn, F.; Nolan, S. P. Org. Biomol. Chem., 2019, 17, 3805–3811.
553. “Synthesis of di-substituted alkynes via palladium-catalyzed decarboxylative coupling and C-H activation.” Gómez-Herrera, A.; Nahra, F.; Wu, J.; Izquierdo, F.; Brill, M.; Cazin, C. S. J.; Nolan, S. P., Chem. Select, 2019, 4, 5–9.
552. “A Simple NMR Method for Determining the s-Donor Properties of N-Heterocyclic Carbenes" Meng, G.; Kakalis, L.; Nolan, S. P.; Szostak, M. Tetrahedon Let., 2019, 60, 378-381.
551. “Synthesis and characterization of Au(I)- and Au(III)-isothiourea complexes and their catalytic and biological activity” Gasperini, D.; Imad, R.; Siddiqui, S.; Malik, A.; Arshad, F.; Choudhary, M. I.; Al-Majid, A.; Cordes, D. B.; Slawin, A. M. Z.; Nolan, S. P.; Smith, A. D. Chem. Eur. J., 2019, 25, 1064-1075.
2018
550. “Well-Defined Palladium(II)–NHC Precatalysts for Cross-Coupling Reactions of Amides and Esters by Selective N–C/O–C Cleavage.” Shi, S.; Nolan, S. P.; Szostak, M. Acc. Chem. Res., 2018, 51, 2589-2599.
549. “Chiral Carbophilic Gold Lewis Acid Complexes in Enantioselective Catalysis” Brill, M.; Nolan, S. P. in Topics in Organometallic Chemistry, Mikami, K. (Ed.) 2018, 62, Springer, Berlin Heidelberg, pp 51-90.
548. “The Activity of Indenylidene Derivatives in Olefin Metathesis Catalysts” Voccia, M.; Nolan, S. P.; Cavallo, L.; Poater, A. Beilstein J. Org. Chem., 2018, 14, 2956-2963.
547. “In Vitro Anti-Atherogenic Properties of N-Heterocyclic Carbene Aurate(I) Compounds” Sioriki, E.; Lordan, R.; Nahra, F.; Van Hecke, K.; Zabetakis, I.; Nolan, S.P. ChemMedChem, 2018, 13, 2484-2487.
546. “The effect of shear flow on microreactor clogging.” Sicignanoa, L.; Tomaiuoloa, G.; Perazzoa, A.; Maffettonea, P. L.; Nolan, S. P.; Guido, S. Chem. Eng. J., 2018, 341, 639-647.
545. “Metallate Complexes of the Late Transition Metals: Organometallic Chemistry and Catalysis.” Gómez-Suárez, A.; Nelson, D. J.; Nolan, S. P. in Adv. Organomet. Chem. Perez, P. J. (Ed) Academic Press, Cambridge USA, 2018, 69, 283-327.
544. “Towards Environmentally Friendlier Suzuki-Miyaura Reactions with Precursors of Pd-NHC (NHC = N-Heterocyclic Carbene) Complexes.” Zinser,C.M.; Warren, K. G.; Meadows, R. E.; Nahra, F.; Al-Majid, A. M.; Barakat, A. M.; Islam, M. S.; Nolan, S. P.; Cazin, C. S. J. Green Chem., 2018, 20, 3246-3252.
543. “Mechanistic Study of the Suzuki-Miyaura Cross-Coupling Reactions of Amide Substrates Mediated by [Pd(NHC)(allyl)Cl] Precatalysts.” Li, G.; Lei, P.; Szostak, M.; Casals-Cruañas, E.; Poater, A.; Cavallo, L.; Nolan, S. P. ChemCatChem, 2018, 10, 3096-3106.
542. “N-Heterocyclic Carbenes” Ramon, R. S.; Nolan, S. P. in “Applied Homogeneous Catalysis with Organometallic Compounds.” Cornils, B.; Herrmann, W.A.; Beller, M.; Paciello, R. (Eds.), Wiley-VCH 2018, 1758p
541. “Synthesis, Characterization and Catalytic Activity of NHC Gold(I) Polyoxometalate Complexes.” Sirindil, F.; Nolan, S. P.; Dagorne, S.; Pale, P.; Blanc, A.; de Frémont, P. Chem Eur. J., 2018, 24, 12630-12637.
540. “PMO-immobilized Au(I)-NHC complexes: Heterogeneous catalysts for sustainable processes.” De Canck, E.; Nahra, F.; Bevernaege, K.; Vanden Broeck, S.; Maes, D.; Nolan, S. P.; Van Der Voort, P. ChemPhysChem., 2018, 19, 430-436.
539. “Insights into the catalytic activity of [Pd(NHC)(cin)Cl] (NHC = IPr, IPrCl, IPrBr) complexes in the Suzuki-Miyaura reaction.” Izquierdo, F.; Zinser, C.; Minenkov, Y.; Cordes, D. B.; Slawin, A. M. Z.; Cavallo, L.; Nahra, F.; Cazin, C. S. J.; Nolan, S. P. ChemCatChem, 2018, 10, 601-611.
538. “Ligand-directed Reactivity in Dioxygen and Water Binding to cis-[Pd(NHC)2(2-O2)]” Palluccio, T. D.; Cai, X.; Majumdar, S.; Farias-Serafim, L.; Tomson, N. C.; Wieghardt, K.; Cazin, C. S. J.; Nolan, S. P.; Rybak-Akimova, E. V.; Fernández-González, M. A.; Temprado, M.; Captain, B.; Hoff, C. D. J. Am. Chem. Soc. 2018, 140, 264-276.
537. “General Method for the Suzuki-Miyaura Cross-Coupling of Primary Amides Enabled by [Pd(NHC)(cin)Cl] at Room Temperature.” Lei, P.; Meng, G.; Ling, Y.; An, J.; Nolan, S. P.; Szostak, M. Org. Let. 2017, 19, 6510-6513.
536. “N-Heterocyclic Carbenes” Ramon, R. S.; Nolan, S. P. in “Applied Homogeneous Catalysis with Organometallic Compounds.” Cornils, B.; Herrmann, W. A.; Beller, M.; Paciello, R. (Eds.), Wiley-VCH 2017, 1758p.
535. “Hydroxide Complexes of the Late Transition Metals: Organometallic Chemistry and Catalysis.” Nelson, D. J.; Nolan, S. P. Coord. Chem. Rev. 2017, 353, 278-294.
534. “Mechanism of the Catalytic Carboxylation of Alkylboronates with CO2 using Ni-NHC complexes: A DFT Study.” Delarmelina, M.; Marelli, E.; Walkimar de M. Carneiro, J.; Nolan, S. P.; Bühl, M. Chem. Eur. J. 2017, 23, 14954-14961.
533. “N-Heterocyclic Carbene Complexes of Palladium in Oxygen Atom Transfer Reactions Involving the Making and Breaking of N-O Bonds.” Cai, K.; Majumdar, S.; Ferias Serafim, L.; Temprado, M.; Nolan, S. P.; Cazin, C. S. J.; Captain, B.; Hoff, C. D. Inorg. Chim. Acta 2017, 468, 285-293. (Invited contribution for Professor Luis Echegoyen special issue)
532. “Expedient Syntheses of Neutral and Cationic Au(I)-NHC Complexes” Veenboer, R. M. P.; Gasperini, D.; Cordes, D. B.; Slawin, A. M. Z.; Cazin, C. S. J.; Nolan, S. P. Organometallics, 2017, 36, 3645-3653.
531. “Transition Metal Complexes and Ligand Synthesis” Nelson, D. J.; Nolan S. P. In Contemporary Catalysis: Science Technology and Applications. Kamer, P. C. J.; Vogt, D.; Thybaut, J. W. (Eds.) RSC Press, 2017, p 396-415.
530. “Inner-sphere versus outer-sphere coordination of BF4- in a NHC-gold(I) complex: implications on reactivity and catalysis.” Veenboer, R. M. P.; Collado, A.; Dupuy, S.; Lebl, T.; Falivene, L.; Cavallo, L.; Cordes, D. B.; Slawin, A. M. Z.; Cazin, C. S. J.Nolan, S. P. Organometallics 2017, 36, 2861-2869.
529. “Ruthenium-catalysed decomposition of formic acid: fuel cell and catalytic applications”
Piola, L.; Fernández-Salas, J. A.; Nahra, F.; Poater, A.; Cavallo, L.; Nolan, S. P. Mol. Cat. 2017, 440, 184-189.
528. “In Vitro Biological Activities of Gold (I)- and Gold (III)-bis(N-Heterocyclic Carbene) Complexes.”Al-Majid, A. M.; Choudhary, M. I.; Yousuf, S.; Jabeen, A.; Imad, R.; Javeed, K.; Shaikh, N. N.; Collado, A.; Nahra, F.; Nolan, S. P. Chem. Select 2017, 2, 5316-5320.
527. “A Simple Synthetic Entryway into Palladium Cross-Coupling Catalysis.” Zinser, C. M.; Nahra, F.; Brill, M.; Meadows, R. E.; Cordes, D. B.; Slawin, A. M. Z.; Cazin, C. S. J.; Nolan, S. P. Chem. Comm. 2017, 53, 7990-7993.
526. “Mechanism of the Suzuki-Miyaura cross-coupling reaction Mediated by [Pd(NHC)(allyl)Cl] Precatalysts.” Meconi, G. M.; Vummaleti, S.; Belanzoni, P.; Nolan, S. P.; Jacobsen, H.; Cavallo, L.; Solà, M.; Poater, A. Organometallics, 2017, 36, 2088-2095.
525. “Mild, aqueous α-arylation of ketones: towards new chemical diversification tools for application to metabolites and drug molecules.” Renault, Y.; Sharma, S. V.; Marelli, E.; Nolan, S. P.; Goss, R. J. M. Chem. Eur. J. 2017, 23, 3832-3836.
524. “POM@IL-MOFs - inclusion of POMs in ionic liquid modified MOFs to produce recyclable oxidation catalysts.” Abednatanzi, S.; Leus, K.; Derakhshande, P. G.; Nahra, F.; De Keukeleere, K.; Van Hecke, K.; Van Driessche, I.; Abbasi, A.; Nolan, S. P.; Van der Voort, P. Cat. Sci. Tech. 2017, 7,1478-1487.
523. “Quantifying and understanding the steric properties of N-heterocyclic carbenes.” Gómez-Suárez, A.; Nelson, D. J.; Nolan, S. P. Chem. Comm. 2017, 53, 2650-2660. (Feature Article)
522. “Gold-N-Heterocyclic Carbene Complexes of Mineral Acids ” Brill, M.; Nahra, F.; Gómez-Herrera, A.; Zinser, C.; Cordes, D. B.; Slawin, A. M. Z.; Nolan, S. P. Chemcatchem 2017, 9, 117-120.
521. “A New Initiating System Based on [Ru(SIMes)(PPh3)(Ind)Cl2] Combined with Azobisisobutyronitrile in the Polymerization and Copolymerization of Styrene and Methylmethacrylate.” Al-Majid, A. M.; Shamsan, W. S.; Al-Odayn, A.-B. M.; Nahra, F.; Aouak, T.; Nolan, S. P. Design Mon. Polym. 2017, 20, 167-176.
519. “Sequential functionalisation of alkynes and alkenes catalysed by Au(I)- and Pd(II)-NHC complexes.” Gómez-Herrera, A.; Nahra, F.; Brill, M.; Nolan, S. P.; Cazin, C. S. J. ChemCatChem. 2016, 8, 3381-3388.
518. “A Switchable Gold Catalyst by Encapsulation in a Self-Assembled Cage.” Jans, A. C. H.; Gómez-Suárez, A.; Nolan, S. P.; N. H. Reek, J. N. H. Chem. Eur. J. 2016, 22, 14836–14839.
517. “Synthesis, characterization and catalytic activity of stable [(NHC)H][ZnXY2] (NHC = N-Heterocyclic carbene, X, Y = Cl, Br) species.” Santoro, O.; Nahra, F.; Cordes, D. B.; Slawin, A. M. Z.; Nolan, S. P.; Cazin, C. S. J. J. Mol. Cat. A. 2016, 423, 85-91.
516. “Synthesis of AuI- and AuIII-Bis(NHC) Complexes: Ligand Influence on Oxidative Addition to AuI Species.” Collado, A.; Bohnenberger, J.; Oliva-Madrid, M.-J.; Nun, P.; Cordes, D. B.; Slawin, A. M. Z.; Nolan, S. P. Eur J. Inorg. Chem., 2016, 4111-4122.
515. “Synthesis, structure and catalytic activity of NHC-AgI carboxylate complexes.” Wong, V. H. L.; Vummaleti, S. V. C.; Cavallo, L.; White, A. J. P.; Nolan, S. P.; Hii, K. K. Chem. Eur. J. 2016, 22, 13320-13327.
514. “Sonication assisted synthesis of (E)-2-methyl-but-2-enyl nucleoside phosphonates prodrugs.” Bessières, M.; Sari, O.; Roy, V.; Nolan, S. P.; Snoeck, R.; Andrei, G.; Schinazi. R. F.; Agrofoglio. L. A. Chem. Select 2016, 1, 3108-3113.
513. “Grignard Reagents and Palladium” Nelson, D. J.; Cazin, C. S. J.; Nolan, S. P. in Grignard Reagents and Transition Metal Catalysts, J. Cossy(ed), Walter de Gruyter, Berlin, 2016, pp 1-60. DOI: https://doi.org/10.1515/psr-2016-0018.
512. “Sustainable Homogeneous Gold Catalysis.” Collado, A.; Gómez-Suárez, A.; Nolan S. P. In Sustainable Catalysis: With Non-endangered Metals, Part 2. RSC Green Chemistry Series, North, M. (Ed.) vol 39, 2016. 41-90.
511. “How easy is CO2 fixation by M-C bond containing complexes (M = Cu, Ni, Co, Rh, Ir)?” Vummaleti, S. V. C.; Talarico, G.; Nolan, S. P.; Cavallo, L.; Poater, A. Org. Chem. Front. 2016, 3, 19-23.
510. “Catalytic α-arylation of imines leading to N-unprotected indoles and azaindoles.” Marelli, E.; Corpet, M.; Minenkov, Y.; Neyyappadath, R. M.; Bismuto, A.; Buccolini, G.; Curcio, M.; Cavallo, L.; Nolan, S. P. ACS Catal. 2016, 6, 2930-2938.
509. “In Silico Olefin metathesis with Ru-based catalysts containing N-heterocyclic carbenes bearing C60 fullerenes” Martínez, J. P.; Vummaleti, S. V. C.; Falivene, L.; Nolan, S. P.; Cavallo, L.; Solà, M.; Poater, A. Chem. Eur. J., 2016, 22, 6617-6623.
508. “1,3-Bis(2,6-diisopropylphenyl)-imidazol-2-ylidene-update.” Nelson, D. J.; Nolan, S. P. Encyclopedia of Reactions in Organic Synthesis (eEROS), 2016, DOI: 10.1002/047084289X.rn00393 (online article).
507. “Recyclable NHC Catalyst for the Development of a Generalized Approach to Continuous Buchwald-Hartwig Reaction and Work-Up” Chartoire, A.; Claver, C.; Corpet, M.; Krinsky, J.; Mayen, J.; Nelson, D. J.; Nolan, S. P.; Peñafiel, I.; Woodward, R.; Meadows, R. E. Org. Proc. Res. Devel., 2016, 20, 551–557.
506. “Gold-NHC complexes as potent bioactive compounds.” Al-Majid, A. M.; Yousuf, S.; Choudhary, M. I.; Collado, A.; Nahra, F.; Nolan, S. P. Chem. Select 2016, 1, 76-80.
505. “The mechanism of transmetalation of organosilanes to gold.” Falivene, L.; Nelson, D. J.; Dupuy, S.; Nolan, S. P.; Poater, A.; Cavallo, L. Chem. Open 2016, 5, 60-64.
504. “Synchrotron Infrared Microspectroscopic Measurement in an Engineered Microfluidic Reactor.” Silverwood, I. P.; Al-Rifai, N.; Nelson, D. J.; Chutia, A.; Wells, P. P.; Nolan, S. P.; Frogley, M. D.; Gavriilidis, A.; Catlow, C. R. A. Rev. Sci. Inst., 2016, 87, 024101-1-5.
503. “Scope and Limitations of the Dual Gold-Catalysed Hydrophenoxylation of Alkynes.” Gómez-Suárez, A.; Oonishi, Y.; Martin, A. R.; Nolan, S. P. Beilstein. J. Org. Chem. 2016, 12, 172-178.
502. “On the Mechanism of the Digold(I) Hydroxide-Catalyzed Hydrophenoxylation of Alkynes.” Gómez-Suárez, A.; Oonishi, Y.; Martin, A. R.; Vummaleti, S. V. C.; Nelson, D. J.; Cordes, D. B.; Slawin, A. M. Z.; Cavallo, L.; Nolan, S. P.; Poater, A. Chem. Eur. J. 2016, 22, 1125-1132.
501. “Transition-Metal Bifluoride Complexes.” Nahra, F.; Brill, M.; Gómez-Herrera, A.; Cazin, C. S. J.; Nolan, S. P. Coord. Chem. Rev. 2016, 259, 65-80.
